Conrad Goodwin

Inorganic and Organometallic Chemistry


Papers (Click title for a link, or copy the DOI)
2018

13. C. A. P. Goodwin, D. Reta, F. Ortu, J. Liu, N. F. Chilton*, D. P. Mills*, Terbocenium: completing a heavy lanthanide metallocenium cation family with an alternative anion abstraction strategy, Chem. Commun., 54, 23, 9182, DOI: 10.1039/C8CC05261A.

12. H. M. Nicholas, C. A. P. Goodwin, J. G. C. Kragskow, S. J. Lockyer, D. P. Mills*, Structural Characterization of Lithium and Sodium Bulky Bis(silyl)amide Complexes, Molecules, 2018, 23, 1138, DOI: 10.3390/molecules23051138.

11. C. A. P. Goodwin, B. L. L. RĂ©ant, J. G. C. Kragskow, I. M. DiMucci, K. M. Lancaster*, D. P. Mills*, S. Sproules*, Heteroleptic Sm(III) halide complexes probed by fluorescence-detected L3-edge X-ray absorption spectroscopy, Dalton Trans., 2018, DOI: 10.1039/c8dt01452c.

10. J.-D. Leng, C. A. P. Goodwin, I. J. Vitorica-Yrezabal, D. P. Mills*, Salt metathesis routes to homoleptic near-linear Mg(II) and Ca(II) bulky bis(silyl)amide complexes, Dalton Trans., 2018, DOI: 10.1039/c8dt00802g.

9. C. A. P. Goodwin, F. Tuna, E. J. L. McInnes, D. P. Mills*, Exploring Synthetic Routes to Heteroleptic UIII, UIV and ThIV Bulky Bis(silyl)amide Complexes, Eur. J. Inorg. Chem., 2018, DOI: 10.1002/ejic.201800036.


2017

8. C. A. P. Goodwin, D. Reta, F. Ortu, N. F. Chilton*, D. P. Mills*, Synthesis and Electronic Structures of Heavy Lanthanide Metallocenium Cations, J. Am. Chem. Soc., 2017, 139, 18714, DOI: 10.1021/jacs.7b11535.

7. C. A. P. Goodwin, F. Ortu, D. Reta, N. F. Chilton*, D. P. Mills*, Molecular magnetic hysteresis at 60 K in dysprosocenium, Nature, 2017, 548, 439, DOI: 10.1038/nature23447.

6. C. A. P. Goodwin, N. F. Chilton, L. S. Natrajan, M.-E. Boulon, J. W. Ziller, W. J. Evans, D. P. Mills*, Investigation into the Effects of a Trigonal-Planar Ligand Field on the Electronic Properties of Lanthanide(II) Tris(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb), Inorg. Chem., 2017, 56, 5959, DOI: 10.1021/acs.inorgchem.7b00664.


2016

5. C. A. P. Goodwin, N. F. Chilton, G. F. Vettese, E. Moreno Pineda, I. F. Crowe, J. W. Ziller, R. E. P. Winpenny, W. J. Evans, D. P. Mills*, Physicochemical properties of near-linear Ln(II) bis-silylamide complexes (Ln = Sm, Eu, Tm, Yb), Inorg. Chem., 2016, 55, 10057, DOI: 10.1021/acs.inorgchem.6b00808.

4. C. A. P. Goodwin, A. Smith, F. Ortu, I. J. Vitorica-Yrezabal, D. P. Mills*, Salt metathesis versus protonolysis routes for the synthesis of silylamide Hauser base (R2NMgX; X = halogen) and amido-Grignard (R2NMgR) complexes, Dalton Trans., 2016, 45, 6004, DOI: 10.1039/C5DT02535D.


2015

3. C. A. P. Goodwin, K. C. Joslin, S. J. Lockyer, A. Formanuik, G. A. Morris, F. Ortu, I. J. Vitorica-Yrezabal, D. P. Mills*, Homoleptic Trigonal Planar Lanthanide Complexes Stabilized by Superbulky Silylamide Ligands, Organometallics, 2015, 34, 2314, DOI: 10.1021/om501123e.

2. N. F. Chilton, C. A. P. Goodwin, D. P. Mills*, R. E. P. Winpenny, The first near-linear bis(amide) f-block complex: a blueprint for a high temperature single molecule magnet, Chem. Commun., 2015, 51, 101, DOI: 10.1039/C4CC08312A.

1. C. A. P. Goodwin, F. Tuna, E. J. L. McInnes, S. T. Liddle, J. McMaster, I. J. Vitorica-Yrezabal, D. P. Mills*, [UIII{N(SiMe2tBu)2}3]: A Structurally Authenticated Trigonal Planar Actinide Complex, Chem. Eur. J., 2014, 20, 14579, DOI: 10.1002/chem.201404864.



Book Chapters
1. Silylamides: towards a half-century of stabilising remarkable f-element chemistry; C. A. P. Goodwin, D. P. Mills, in Periodical Reports: Organometallic Chemistry: Volume 41, Eds. I. J.S. Fairlamb, J. Lynam, N. J. Patmore, P. Elliott, RSC Publishing, Cambridge, UK, 2017, 123, ISBN: 978-1-78262-416-5, DOI: 10.1039/9781782626923-00123.

Chemistry Division, Los Alamos National Laboratory,
Los Alamos, N.M.
Office: 48-208 e: cgoodwin@lanl.gov
t: (505) 551-2837 | (505) 665-6931